A hexanuclear iron(III) complex [Fe6O2(OH)2(PhCOO)10(hedmp)2] . 3CH3CN assembled from 2-hydroxyethyl-3,5-dimethyl pyrazole Article - 2010

Ramaswamy Murugavel, Nayanmoni Gogoi, Rana Howlader, Rodolphe Clérac

Ramaswamy Murugavel, Nayanmoni Gogoi, Rana Howlader, Rodolphe Clérac, « A hexanuclear iron(III) complex [Fe6O2(OH)2(PhCOO)10(hedmp)2] . 3CH3CN assembled from 2-hydroxyethyl-3,5-dimethyl pyrazole  », Inorganica Chimica Acta, 2010, pp. 3004-3009. ISSN 0020-1693

Abstract

In order to assemble polynuclear iron(III) complexes, the coordination chemistry of the 2-hydroxyethyl- 3,5-dimethylpyrazole (hedmp-H) ligand has been investigated. Reaction of hedmp-H with trinuclear iron carboxylate precursor [Fe3O(PhCOO)6(H2O)3]Cl in acetonitrile yielded the hexanuclear Fe(III) complex [Fe6O2(OH)2(PhCOO)10(hedmp)2].3CH3CN (1). This aggregate has been characterized by employing various analytical techniques, spectroscopic studies and single crystal X-ray diffraction. Detailed magnetic susceptibility measurements revealed that 1 displays an ST = 5 ground state.

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