A Tetranuclear, Macrocyclic 3d-4f Complex Showing Single-Molecule Magnet Behavior Article - 2011

Humphrey L. C. Feltham, Rodolphe Clérac, Annie K. Powell, Sally Brooker

Humphrey L. C. Feltham, Rodolphe Clérac, Annie K. Powell, Sally Brooker, « A Tetranuclear, Macrocyclic 3d-4f Complex Showing Single-Molecule Magnet Behavior  », Inorganic Chemistry, 2011, pp. 4232-4234. ISSN 0020-1669

Abstract

[CuII3TbIII(LPr)(NO3)2(MeOH)(H2O)2]-(NO3) 3 3H2O is a rare example of a 3d-4f single-molecule magnet prepared using a macrocyclic ligand : at low T, it exhibits frequency-dependent alternating-current susceptibility, indicative of slow relaxation of the magnetization.

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