Coordination Complexes of P-Containing Polycyclic Aromatic Hydrocarbons : Optical Properties and Solid-State Supramolecular Assembly Article - 2017

François Riobé, Rózsa Szűcs, Christophe Lescop, Régis Réau, László Nyulászi, Pierre-Antoine Bouit, Muriel Hissler

François Riobé, Rózsa Szűcs, Christophe Lescop, Régis Réau, László Nyulászi, Pierre-Antoine Bouit, Muriel Hissler, « Coordination Complexes of P-Containing Polycyclic Aromatic Hydrocarbons : Optical Properties and Solid-State Supramolecular Assembly  », Organometallics, 2017, pp. 2502–2511. ISSN 0276-7333

Abstract

A series of complexes including sigma3,lambda3-P-modified PAH as a ligand have been prepared showing that the ligand possesses a classical “phosphine like” reactivity. The use of different metals (Pd(II), Cu(I), Re(I), Au(I)) having different coordination number allows to tune the optical properties of the complexes, which is dominated basically by the electronic transitions of the ligand itself. The study of the solid state properties by mean of X-ray diffraction also shows that the combination of coordination chemistry and pi-stacking interactions between the PAH ligand allows to obtain a great diversity of solid state structures.

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