Photoinduced reversible spin-state switching of an Fe III complex assisted by a halogen-bonded supramolecular network Article - 2017

Ie-Rang Jeon, Corine Mathonière, Rodolphe Clérac, Mathieu Rouzières, Olivier Jeannin, Elzbieta Trzop, Eric Collet, Marc Fourmigué

Ie-Rang Jeon, Corine Mathonière, Rodolphe Clérac, Mathieu Rouzières, Olivier Jeannin, Elzbieta Trzop, Eric Collet, Marc Fourmigué, « Photoinduced reversible spin-state switching of an Fe III complex assisted by a halogen-bonded supramolecular network  », Chemical Communications, 2017, pp. 10283-10286. ISSN 1359-7345

Abstract

The organization of a molecular FeIII complex embedded in a halogen bonded 2D network is chemically tuned to trigger temperature- and light-induced spin-state switching. We attribute the associated magnetic properties and the unprecedented photoswitching effect to the optimized structural confinement provided by the presence of the supramolecular host framework.

Voir la notice complète sur HAL

Actualités