Teaching an old molecule new tricks Evidence and rationalisation of the slow magnetisation dynamics in [DyTp2Acac] Article - 2018

Frédéric Guégan, François Riobé, Olivier Maury, Julie Jung, Boris Le Guennic, Christophe Morell, Dominique Luneau

Frédéric Guégan, François Riobé, Olivier Maury, Julie Jung, Boris Le Guennic, Christophe Morell, Dominique Luneau, « Teaching an old molecule new tricks Evidence and rationalisation of the slow magnetisation dynamics in [DyTp2Acac]  », Inorganic Chemistry Frontiers, 2018, pp. 1346-1353. ISSN 2052-1553

Abstract

We report the luminescence and magnetic properties of the mononuclear Dy(iii) complex [DyTp2Acac] (Tp = tris-pyrazolylborohydride and Acac = 2,4-pentanedionate). This complex displays peculiar slow magnetisation dynamics at low temperature in the absence of a static field, which we managed to interpret using its resolved luminescence spectrum and ab initio calculations.

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